Face‐Directed Tetrahedral Organic Cage Anchored Palladium Nanoparticles for Selective Homocoupling Reactions

The Cover Feature shows the formation of two face-directed truncated tetrahedral enantiopure organic cages by employing dynamic imine condensation reactions a hexa-aldehyde precursor with trans-oriented diamines separately. In view its intrinsic porosity combined presence multiple vicinal di-imine corners and stable aromatic backbones, one was used as template for nucleation ultrafine Pd-nanoparticles (PdNPs). cage-PdNPs hybrid further utilized suitable catalyst selective additive-free C−C homocoupling aryl heteroaryl halides under heterogeneous conditions. Moreover, composite material exhibited high durability thermal stability several catalytic cycles without any agglomeration. More information can be found in Research Article P. S. Mukherjee co-workers.